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MICROBIOLOGICAL TECHNOLOGIES


MICROBIOLOGICAL METHOD FOR ARPD REMOVAL FROM THE PRODUCING WELLS

The intensive paraffin deposition in the field equipment shortens its overhaul life and requires rather complicated and expensive operation. The technology is recommended for the producing wells equipped with the sucker-rod pumps. Removal of paraffin deposits from the well equipment and bottom-hole zone is based on employment of the aerobic hydrocarbon-oxidizing bacteria oxidizing and making paraffin oil hydrocarbons movable. Vital activity of the hydrocarbon-oxidizing microorganisms results in formation of substances having combined ARPD decomposing, removing and inhibiting properties. The microbiological method for paraffin control is new but it has found use both abroad and in Tatarstan.

The technology has been employed in NGDU "Bavlyneft" on a large scale. Altogether more than 150 wells were treated in JSC "Tatneft". Economic return is 1 - 1.5 thousand roubles per 1 producing well. The scraping interval of producing wells increases from 1-2 up to 2-12 months.

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BIOTECHNOLOGICAL METHOD FOR IMPROVED OIL RECOVERY BY RESERVOIR SYNTHESIS OF OIL-DISPLACING AGENTS

The method is recommended for the highly encroached fields (90-95%) at the later stage of exploitation. The method comprises an increase in efficiency of residual oil displacement from the flooded reservoirs using the oil-displacing agents - the products of vital functions of microorganisms formed directly in pore space of the oil reservoirs by stimulation of the microflora populating formation fluids of the flooded fields. If the reservoir microflora is absent the suitable microorganisms are injected.

The technology comprises 4 cycles for the injection of salts, biostimulator and hydrocarbon-oxidizing bacteria (HOB). 1 - 2 cycles involve the injection of aerated salt solutions and biostimulator stimulating the bacteria causing the degradation of residual hydrocarbons in the bottom-hole formation zone and the formation of low-molecular fatty acids, alcohols, aldehydes and biopolymers from them. 3 - 4 cycles involve the injection of salt solution stimulating other microflora causing the formation of gaseous oil-displacing agents.

The intermediate products of microorganisms’ vital functions become the new oil-displacing agents such as CH4, CO2, H2 and N2 as they travel through the reservoir. The alternation of the aerated salt solutions’ injection and conventional waterflooding promotes travel of the oil-displacing agents’ system through the reservoir towards the producing wells.

The incremental oil production amounts 37% of total production in the area by using the technology. The technology is cheap, available, simple and ecologically safe, it is used employing the equipment availiable in the field.

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TECHNOLOGY FOR OIL POLLUTION REMOVAL FROM BASINS AND SOIL BY COMBINED METHOD USING HYDROCARBON-OXIDIZING BACTERIA

The technology is based on preliminary oil gathering by the mechanical method and further application of adsorbent with oil as a fuel or destruction of adsorbent by microorganisms.

The mechanical method being primary is used for treating water surface, waterside part of basins and soil at high degree of pollution and fuel oil fouling. The method involves mechanical gathering of oil products, their decantation from water or soil and preparation for utilization. Oil skimmers (desilters), soil rippers with floating barriers, decantation and dewatering units, reagent assembly, mobile treating facilities are used for this purpose.

The oil products can be gathered both from soil surface and water surface with adsorbent. The adsorption capacity ranges from 6 to 8 g/g depending on oil viscosity. The oil product gathered with the adsorbent can easily regenerate or decompose with microorganisms if required.

We use the adsorbent of combined action containing basically the hydrocarbon-oxidizing bacteria (HOB) and other bacteria for specific pollution. They are able to decompose oil and adsorbent to ecologically neutral compounds or to transform into water-soluble organic compounds up to their complete oxidation to CO2 and water. The booms of adsorbents with HOB trapping oil are placed for treating water surface.

The adsorbent can be removed or left for biodegradation on the surface depending on the specified conditions after their oil saturation. The treatment of the oil-polluted areas is started at the end of April - at the beginning of May (depending on the climatic conditions) and then the cyclic soil treatment is carried out with 20-30 days’ interval.

The conventional facilities and ecologically safe and readily available reagents have been used for the treatment of the oil-polluted area. The technology for soil treatment has been successfully used in West Siberia and Tatarstan.

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COMBINED TECHNOLOGY FOR OIL POLLUTION REMOVAL FROM BASINS AND SOIL

The technology is used for oil products’ gathering during workover and for utilization of accidentally spilled liquid oil products: motor oil of various grades, crude oil, fuel oil, diesel oil etc.

The technology comprises:

  • mechanical and adsorptive gathering of oil products from soil and water surface. The spilled oil products can be gathered from soil and water surface with adsorbent by powder spraying or with adsorptive elements in a form of mats and booms;
  • complete recultivation of soil by the bioadsorptive method.

The oil product can be regenerated after the mechanical and adsorptive gathering. Consumer goods can be made of double adsorbent-oil product mass if required. The adsorbents are ecologically safe, they are made of readily available raw materials and certified. Their large- scale production has been arranged.

The mechanical treating method is used for severe oil pollution. The conventional facilities are used for treatment of the oil-polluted areas. Soil is recultivated in April - October.

Characteristics
Appearance powder or flat elements in a form of ribbons and mats
Adsorption capacity, g/g not less than 2-8 (viscosity of oil product is not more than 40 mm2/s)
Specific mass, g/cm3 0,6-0,85
Period of complete soil recultivation not more than 10 months (temperature of soil is not more than 10°C)
Guaranty period:
- mechanical adsorbent
- biological adsorbent

unlimited when normal storage conditions are obeyed
not more than a year

The technology for soil and water surface treatment was patented and has been successfully used in West Siberia, Samara region and Tatarstan.

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COMBINED TECHNOLOGY FOR APPLICATION OF FIBER-DISPERSION SYSTEM AND MICROORGANISMS FOR IMPROVED OIL RECOVERY

The technology is used for improved oil recovery from the flooded heterogeneous formations under the conditions of ultimate water content of produced fluids at the later stage of the oil field development.

When the technology is employed oil recovery increases by an increase of the sweep efficiency and by higher degree of the oil sweepout applying the products of microorganisms’ vital functions.

The reagent included into the composition has high selectivity, substantially increases filtration resistance of the encroached flushed formation zones, promotes filtration redistribution in the formation and sweeping of the unswept intervals.

The  technology comprises the successive-alternate injection of the medium-volume slug of the aqueous suspensions of wood flour, microorganisms, inorganic salt and clay powder through the injection wells into the reservoir. The oil-driving agents: fatty acids, alcohols, aldehydes, biopolymers, CH4, CO2, H2 and N2 promoting incremental oil displacement form in the formation within 15-20 days of the composition injection as a result of microorganisms’ vital functions.

The technology is ecologically safe, available and simple and it doesn’t require expensive and unavailable reagents. The standard field equipment is employed for the formation treatment. 1000-1200 t of incremental oil is produced per 1 producing well by employing the technology.

Incremental oil production is 30-78% of total production in the area having 1 injection and 4 producing wells.

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LABORATORY SET FOR ANALYSES

The set is used for determination of the level of sulfate reducing bacteria (SRB) contamination of the oil-field systems and for evaluation of the performance of the reagents inhibiting microbiological corrosion.

The secondary oil recovery by waterflooding is accompanied by contamination of the producing formations with microorganisms, particularly such corrosion-hazardous as sulfate reducing bacteria (SRB).

Development of SRB biocenosis in the producing formation causes formation of hydrogen sulfide and more severe corrosion processes. The pipes’ life is 10-12 years but they can fail within 2-3 years because of microbiological corrosion. Hence, monitoring of SRB contamination level of the oil-field systems is an important and necessary operation.

To promote monitoring of SRB contamination level of the oil-field systems NIIneftepromchim arranged the commercial production of the sets containing everything required for making such control by the technicians.The set consists of 20 ml bottles with nutrient for SRB and syringes.

The set can also evaluate the efficiency of the reagents having bactericide properties.

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